Fifteen days of continuous activity survey at Stromboli volcano, Italy, in late September 2000: Doppler radar, seismicity, infrared, soil humidity, and mapping of the crater region     

Nico-Alexander Urbanski  Malte Vöge  Ralf Seyfried  Lars Rüpke  Tanja Petersen  Till Hanebuth  Matthias Hort 《International Journal of Earth Sciences》2002,91(4):712-722

The intention of our study was to gain new insight into the complex interplay between different types of eruption of the Stromboli volcano by combining detailed field observation with different geophysical methods. We recorded more than 600 eruptions by use of continuous Doppler radar measurements. We detected the onset of the seismic precursor and the beginning of the visible eruption by use of seismic and infrared data. Two soil samples per day were used to monitor the effect of humidity on the eruptive style. We mapped the crater region as a reference base for the long-term morphological changes of the active region and for the exact positions of our measurement systems. Two distinct types of eruption were distinguished from each other on the basis of seismic and radar data - short, wide-angle Strombolian explosions and pulsating, sharp angle fountain-like eruptions. Data and visual observations imply that weather conditions significantly effect volcanic activity. We also interpret the intensification of eruptive activity during our field study as replenishment of the reservoir with a new batch of magma in late September 2000.  相似文献   

Analyses of organic and inorganic contaminants in Salton Sea fish   总被引：3，自引：0，他引：3  

Riedel R  Schlenk D  Frank D  Costa-Pierce B 《Marine pollution bulletin》2002,44(5):403-411

Chemical contamination of fish from the Salton Sea, a quasi-marine lake in Southern California, could adversely impact millions of birds using the Pacific Flyway and thousands of humans using the lake for recreation. Bairdiella icistia (bairdiella), Cynoscion xanthulus (orangemouth corvina), and Oreochromis spp. (tilapia) were sampled from two river mouths and two nearshore areas of the Salton Sea. Muscle tissues were analyzed for a complete suite of 14 trace metals and 53 pesticides. Fish muscle tissues had concentrations of selenium ranging between 1.89 and 2.73 microg/g wet weight. 4,4'-DDE accounted for 94% of the total DDT metabolites. Total DDTs ranged between 17.1 and 239.0 and total PCBs between 2.5 and 18.6 ng/g wet weight. PCB congeners 132, 138, 153, 168, and 180 comprised over 50% of the total PCBs. Given the potential implementation of a commercial fishing at the Salton Sea in the future, the presence of persistent organic pollutants and selenium warrants further research into the effects of these mixtures on fish populations, and on wildlife and humans consuming fish.  相似文献   

Climate change and North Sea storm surge extremes: an ensemble study of storm surge extremes expected in a changed climate projected by four different regional climate models   总被引：5，自引：0，他引：5  

Katja Woth  Ralf Weisse  Hans von Storch 《Ocean Dynamics》2006,56(1):3-15

The coastal zones are facing the prospect of changing storm surge statistics due to anthropogenic climate change. In the present study, we examine these prospects for the North Sea based on numerical modelling. The main tool is the barotropic tide-surge model TRIMGEO (Tidal Residual and Intertidal Mudflat Model) to derive storm surge climate and extremes from atmospheric conditions. The analysis is carried out by using an ensemble of four 30-year atmospheric regional simulations under present-day and possible future-enhanced greenhouse gas conditions. The atmospheric regional simulations were prepared within the EU project PRUDENCE (Prediction of Regional scenarios and Uncertainties for Defining EuropeaN Climate change risks and Effects). The research strategy of PRUDENCE is to compare simulations of different regional models driven by the same global control and climate change simulations. These global conditions, representative for 1961–1990 and 2071–2100 were prepared by the Hadley Center based on the IPCC A2 SRES scenario. The results suggest that under future climatic conditions, storm surge extremes may increase along the North Sea coast towards the end of this century. Based on a comparison between the results of the different ensemble members as well as on the variability estimated from a high-resolution storm surge reconstruction of the recent decades it is found that this increase is significantly different from zero at the 95% confidence level for most of the North Sea coast. An exception represents the East coast of the UK which is not affected by this increase of storm surge extremes.  相似文献   

Quantification of carbon flow from stable isotope fractionation in rice field soils with different organic matter content   总被引：1，自引：0，他引：1  

Holger Penning  Ralf Conrad   《Organic Geochemistry》2007,38(12):2058-2069

Rice fields are an important source for the greenhouse gas methane produced by acetoclastic and hydrogenotrophic methanogenesis. Fractionation of ¹³C/¹²C can in principle be used to quantify the relative contribution of these pathways, but our knowledge of isotopic fractionation during reduction of CO₂ and turnover of acetate in different methanogenic environments is still scarce. We therefore measured δ¹³C signatures in two types of anoxic Italian rice field soils, one with high and one with low degradable organic matter (OM) content. Both soils were incubated in the presence and absence of methyl fluoride, a specific inhibitor of acetoclastic methanogenesis. Optimization of methyl fluoride concentration resulted in complete inhibition of acetoclastic methanogenesis. CH₄ was then exclusively produced by hydrogenotrophic methanogenesis, allowing determination of the isotopic signatures and fractionation factors specific for this methanogenic pathway. Acetate, which was then no longer consumed, accumulated and was used for determination of the isotopic signature of the fermentatively produced acetate (both total acetate and methyl carbon of acetate). Hence, all isotopic signatures, including fractionation factors were determined for the methanogenic soil. These data, were then used for computation of the relative contribution of the two methanogenic pathways. In the high OM soil, the contribution of acetoclastic methanogenesis to total CH₄ production increased simultaneously with decreasing acetate concentration. In the low OM soil, methanogenesis from H₂/CO₂ was clearly greater than theoretically expected. Furthermore, isotope fractionation of hydrogenotrophic methanogenesis indicated that the in situ energy status of methanogens strongly depended on the availability of organic carbon in the rice field soil system. Collectively, our data show that the study of isotopic fractionation in methanogenic environments allows a deeper insight into the ongoing processes, which may be quite different in the same ecosystem with different content of degradable OM.  相似文献   

The Bayesian approach to an internally consistent thermodynamic database: theory, database, and generation of phase diagrams     

Niranjan D. Chatterjee  Ralf Krüger  Gerd Haller  Walter Olbricht 《Contributions to Mineralogy and Petrology》1998,133(1-2):149-168

An internally consistent thermodynamic dataset has been derived for 148 endmember phases (145 solids and 3 fluids) comprising the elements Li, Na, K, Be, Mg, Ca, Ti, Cr, Mn, Fe, Zn, Al, Si, C, H, and O. This has been achieved by simultaneous treatment of phase property (like standard enthalpy of formation, standard entropy, molar heat capacity, molar volume, thermal expansivity, bulk modulus etc.) and reaction reversal data by the Bayesian method. The theory underlying the approach, and the computational methods involved, are briefly outlined. (For the benefit of readers unfamiliar with inference statistics, the basic concepts of the Bayes method are also presented in such a way that they can be grasped intuitively.) Although not yet addressed, this method can be extended to refine the thermodynamic mixing properties of crystalline solutions. The sources of the input data, culled from the literature, are summarized in the Appendix. The resulting database is succinctly documented in this paper. It includes the enthalpies of formation and entropies, their uncertainties, and the correlation among them. The database allows calculation of P-T, T-X _CO2, P-X _CO2, and T-f _O2 sections, with error propagation into the computed phase diagrams on a routine basis. A user-friendly computer program has been written to generate such phase diagrams. It is public domain software. The software and the thermodynamic database (which includes a complete documentation of the thermodynamic data above and beyond those listed (Table 2, here) may be downloaded from the web site http://homepage.ruhr-uni-bochum.de/niranjan.chatterjee/Index.htm. Examples of computed phase diagrams are given to illustrate the quality of the data and the capabilities of the software. Received: 11 March 1998 / Accepted: 11 June 1998  相似文献   

Comparison of Galerkin-type discretization techniques for two-phase flow in heterogeneous porous media   总被引：1，自引：0，他引：1  

Rainer Helmig  Ralf Huber 《Advances in water resources》1998,21(8):545

A comparison of Standard Galerkin, Petrov-Galerkin, and Fully-Upwind Galerkin methods for the simulation of two-phase flow in heterogeneous porous media is presented. On the basis of the coupled pressure-saturation equations, a generalized formulation for all three finite element methods is derived and analysed. For flow in homogeneous media, the Petrov-Galerkin method gives excellent results. But this method fails miserably for problems with heterogeneous media. This is because it is not able to capture correctly processes that take place at interfaces when, for instance, the capillary pressure-saturation relationship after Brooks and Corey is assumed. The Fully-Upwind Galerkin method is superior to the Petrov-Galerkin approach because it is able to give correct results for flow in homogeneous and heterogeneous media for the two models of van Genuchten and Brooks-Corey. The widely used formulation which is correct for the homogeneous case cannot be used for heterogeneous media. Instead the straightforward approach of gradp_c in combination with a chord-slope technique must be utilized.  相似文献   

Bounce Rock—A shergottite‐like basalt encountered at Meridiani Planum,Mars     

Jutta ZIPFEL  Bradley L. JOLLIFF  Ralf GELLERT  Kenneth E. HERKENHOFF  Rudolf RIEDER  Robert ANDERSON  James F. BELL III  Johannes BRÜCKNER  Joy A. CRISP  Philip R. CHRISTENSEN  Benton C. CLARK  Paulo A. De SOUZA Jr.  Gerlind DREIBUS  Claude D’USTON  Thanasis ECONOMOU  Steven P. GOREVAN  Brian C. HAHN  Göstar KLINGELHÖFER  Timothy J. McCOY  Harry Y. McSWEEN Jr.  Douglas W. MING  Richard V. MORRIS  Daniel S. RODIONOV  Steven W. SQUYRES  Heinrich WÄNKE  Shawn P. WRIGHT  Michael B. WYATT  Albert S. YEN 《Meteoritics & planetary science》2011,46(1):1-20

Abstract– The Opportunity rover of the Mars Exploration Rover mission encountered an isolated rock fragment with textural, mineralogical, and chemical properties similar to basaltic shergottites. This finding was confirmed by all rover instruments, and a comprehensive study of these results is reported here. Spectra from the miniature thermal emission spectrometer and the Panoramic Camera reveal a pyroxene‐rich mineralogy, which is also evident in Mössbauer spectra and in normative mineralogy derived from bulk chemistry measured by the alpha particle X‐ray spectrometer. The correspondence of Bounce Rock’s chemical composition with the composition of certain basaltic shergottites, especially Elephant Moraine (EET) 79001 lithology B and Queen Alexandra Range (QUE) 94201, is very close, with only Cl, Fe, and Ti exhibiting deviations. Chemical analyses further demonstrate characteristics typical of Mars such as the Fe/Mn ratio and P concentrations. Possible shock features support the idea that Bounce Rock was ejected from an impact crater, most likely in the Meridiani Planum region. Bopolu crater, 19.3 km in diameter, located 75 km to the southwest could be the source crater. To date, no other rocks of this composition have been encountered by any of the rovers on Mars. The finding of Bounce Rock by the Opportunity rover provides further direct evidence for an origin of basaltic shergottite meteorites from Mars.  相似文献   

Volume diffusion of Ytterbium in YAG: thin-film experiments and combined TEM–RBS analysis     

Katharina Marquardt  Elena Petrishcheva  Rainer Abart  Emmanuel Gardés  Richard Wirth  Ralf Dohmen  Hans-Werner Becker  Wilhelm Heinrich 《Physics and Chemistry of Minerals》2010,37(10):751-760

In this study, we address volume diffusion of ytterbium in yttrium aluminum garnet (YAG) using thin-film single crystal diffusion couples. We employ analytical transmission electron microscopy (ATEM) as a tool for combined microstructural and microchemical analysis and compare the results to Rutherford backscattering (RBS) analysis. Given the high spatial resolution of the method, we focus on microstructural changes of the thin-film diffusant source during the diffusion anneal. We evaluate the potential influence of the associated changes in its transport properties on the evolution of concentration profiles in the single crystal substrate. This approach allows us to test the reliability of determination of volume diffusion coefficients from thin-film diffusion experiments. We found that for the chosen experimental setting, the influence of thin-film re-crystallization is small when compared with the experimental uncertainty and good estimates for the volume diffusion coefficients of Yb in YAG can be obtained using standard assumptions. Both Yb-concentration profiles analyzed with ATEM and with RBS give similar results. At 1,450°C and 1 bar, we infer log D _Yb (m²/s) values of −19.37 ± 0.07 (TEM) and −19.84 ± 0.02 (RBS). Although the change in thin-film transport properties associated with successive crystallization during the diffusion anneal does not play a major role for our experimental setup, this effect cannot generally be ignored.  相似文献   

A new pathway for Deep water exchange between the Natal Valley and Mozambique Basin?     

Errol Wiles  Andrew Green  Mike Watkeys  Wilfried Jokat  Ralf Krocker 《Geo-Marine Letters》2014,34(6):525-540

Although global thermohaline circulation pathways are fairly well known, the same cannot be said for local circulation pathways. Within the southwest Indian Ocean specifically there is little consensus regarding the finer point of thermohaline circulation. We present recently collected multibeam bathymetry and PARASOUND data from the northern Natal Valley and Mozambique Ridge, southwest Indian Ocean. These data show the Ariel Graben, a prominent feature in this region, creates a deep saddle across the Mozambique Ridge at ca. 28°S connecting the northern Natal Valley with the Mozambique Basin. Results show a west to east change in bathymetric and echo character across the northern flank of the Ariel Graben. Whereby eroded plastered sediment drifts in the west give way to aggrading plastered sediment drift in the midgraben, terminating in a field of seafloor undulations in the east. In contrast, the southern flank of the Ariel Graben exhibits an overall rugged character with sediments ponding in bathymetric depressions in between rugged sub/outcrop. It is postulated that this change in sea-floor character is the manifestation of deep water flow through the Ariel Graben. Current flow stripping, due to increased curvature of the graben axis, results in preferential deposition of suspended load in an area of limited accommodation space consequently developing an over-steepened plastered drift. These deposited sediments overcome the necessary shear stresses, resulting in soft sediment deformation in the form of down-slope growth faulting (creep) and generation of undulating sea-floor morphology. Contrary to previous views, our works suggests that water flows from west to east across the Mozambique Ridge via the Ariel Graben.  相似文献   

Simulated response to inter-annual SST variations in the Gulf Stream region   总被引：1，自引：1，他引：0  

Ralf Hand  Noel Keenlyside  Nour-Eddine Omrani  Mojib Latif 《Climate Dynamics》2014,42(3-4):715-731

Recent studies show that mid-latitude SST variations over the Kuroshio-Oyashio Extension influence the atmospheric circulation. However, the impact of variations in SST in the Gulf Stream region on the atmosphere has been less studied. Understanding the atmospheric response to such variability can improve the climate predictability in the North Atlantic Sector. Here we use a relatively high resolution (～1°) Atmospheric General Circulation Model to investigate the mechanisms linking observed 5-year low-pass filtered SST variability in the Gulf Stream region and atmospheric variability, with focus on precipitation. Our results indicate that up to 70 % of local convective precipitation variability on these timescales can be explained by Gulf Stream SST variations. In this region, SST and convective precipitation are strongly correlated in both summer (r = 0.73) and winter (r = 0.55). A sensitivity experiment with a prescribed local warm SST anomaly in the Gulf Stream region confirms that local SST drives most of the precipitation variability over the Gulf Stream. Increased evaporation connected to the anomalous warm SST plays a crucial role in both seasons. In summer there is an enhanced local SLP minimum, a concentrated band of low level convergence, deep upward motion and enhanced precipitation. In winter we also get enhanced precipitation, but a direct connection to deep vertical upward motion is not found. Nearly all of the anomalous precipitation in winter is connected to passing atmospheric fronts. In summer the connection between precipitation and atmospheric fronts is weaker, but still important.  相似文献